Polyelectrolyte Complexes Affect Tea Taste and Mouthfeel? – Part 1

Tea has various polyelectrolyte, such as 4 types of catechins in green tea, pectins, polysaccharides, theaflavins and thearubigins in black tea, and so on.

We know these constituents determine tea taste.

In addition, complexes or aggregates of these polyelectrolyte could affect taste and mouthfeel of tea, in my personal opinion.

If laser light is applied to some solution which contain submicron size particles such as polyelectrolyte, the light scatters as depicted in some scientific blogs. We can see a red line of light scattering in the suspension. We obviously find the suspension turbid.

Tea infusion can also scatters laser light as follows, even though its color is clear as we can see through the wood grain of the table.

LightScatteringByTeaInfusion
This means tea infusion contains submicron-size particles, although this tea infusion doesn’t seem to be turbid.

What are these particles?
I guess these could be the complexes or aggregates of tea polyelectrolyte.

Polyelectrolyte can aggregate by some mineral ions such as calcium, ferric ion, etc. and bind such ions making complexes. I think lower infusion rate of tea polyelectrolyte under higher concentration of calcium ion, as clarified by Sipro et al.[140]

I’d like to continue to post such kind of personal speculation.

[140] Spiro M., Price W.E., Miller W.M., Arami M. (1987) :  Kinetics and equilibria of tea infusion: Part 8—the effects of salts and of pH on the rate of extraction of theaflavins from black tea leaf, Food Chemistry 25:117-126

Re-steeping could inspire expressive faces of green tea!

Green tea “Sencha” has a potential to be brewed more than three times.
In Japan, it is recommended to infuse green tea at low temperature at first infusion and then re-steep at higher temperature than the previous infusion. An example of water temperature to infuse deep-steamed green tea “fukamushi cha” is shown as follows.

Conditions-Table

In this condition, extraction behavior of each constituents determining tea taste is shown in the following picture, based on results measured by Sakamoto et al. [089].

InfusionRatio

The first infusion makes us enjoy umami due to amino acids and delicate taste with fresh aroma. In the case of higher grade one, these flavors keep longer and finish smoothly and more gracefully.
The second infusion has a nice balance of umami with bitterness and astringency. In the case of higher grade one, in some minutes after sipping it, aftertaste can keep longer and change to sweet gradually. In the supposition of the author, this grdual change in aftertaste to sweet would be caused by the conformation change of taste-determining polyelectrolyte such as catechins, tannin, saccharides and their complexes, due to the change in their surrounding chemical conditions such as electrochemical potential and oxidation-reduction potential.
The third infusion has more bitter and astringent taste derived from catechins.

In addition to these taste, we can enjoy the change in infusion color also, especially in case of deep-steamed green tea. Till the third infusion, its color is getting deeper green with the progress of re-steeping.

3infusions
As just described, we can find expressive faces of green tea by re-steeping.

Furthermore, we can arrange the flavor of green tea by adjusting water temperature and steeping time based on the extraction kinetics of each taste-determining constitution.

In my personal opinion, I prefer longer infusion time at 1st infusion, resulting in more umami and fine aftertaste for me.

Please try various arrangement of infusion conditions as you like!

 

<Reference>
[089] Sakamoto A., Nakagawa M., Sugiyama H., Horie H. (2002) The compositions of the respective infusions of Sencha brewed three times, Tea Research Journal94:45-55 (in Japanese)