Polyelectrolyte Complexes Affect Tea Taste and Mouthfeel? – Part 2

If a laser light is passed through some suspension which contains submicron or micron order particles, we can see the line of light scattering. For example, a water containing small amount of milk exhibits a red line of light scattering as follows.

MilkLightScattering

The scattered light indicates the information about size, shape and motion of particles suspended in the liquid. Thus, light scattering can be used to measure the size, size distribution and motion of submicron-sized particles [Mat099]. The technique are applied to not only chemical industry but also biological use [156], environmental measurement and food industry etc.

As mentioned and shown previously (Part 1), tea infusion can scatter the laser light, exhibiting the red line of light scattering. Compared with the other liquid having similar color, we can obviously find the difference in the property of light scattering as follows.

EnergyDrinkLightScattering
A liquid left side is an energy drink containing mainly amino acids and vitamins. Its yellow color is derived from vitamin B. Although the color of both liquid are so clear we can see through the wood grain of table, however, only tea infusion does scatter the laser light while energy drink doesn’t scatter.

It is supposed that the difference is caused by the existence of polyelectrolytes sized between micron and submicron order.

We can observe the red line of light scattering in the case of each tea such as black tea, oolong tea, pan-fired tea, and bottled green tea.

EachTeaInfusionLS

Even in the case of a bottled tea, which has been filtrated by porous media to remove or prevent sediments and sedimentation in its manufacturing process.
Based on the of Ito En Ltd.[P001], the components such as polysaccharides and proteins which cause sediments are removed by porous material filtration and silica adsorption. Beside, the patent article describe that D90 is more than 3500 micrometers, indicating that polyelectrolytes still remain in the bottled tea after filtration and adsorption process.

We can observe the aggregation process in a cup of tea, especially in the case of deep-steamed green tea as follows.

ConstituentsSedimentationInGreenTea

Aggregates grow bigger with elapse time, resulting in settling on the bottom of teacup.
This change affected the taste and mouthfeel of tea, I felt.

When I tasted the tea after infusion immediately, I could feel somehow viscous. After sedimentation, the supernatant was seemed be mild and have delicate sweetness, as same as before settling, while it seemed to have lower viscosity compared with before sedimentation. The sediments-rich part seemed to be more viscous and its taste itself seemed to be same as before sedimentation. On the other hand, I felt stronger aftertaste, which changed from slight astringency and green flavor to sweet taste.

This sense is the reason why I suppose polyelectrolytes and their aggregates are essential for the body, aftertaste, mouthfeel of teas.

In the next part, I’d like to show some images about my speculation.

<References>
[Mat099] Williams K. An education material for the biophysics in Yale University.(URL : http://keck.med.yale.edu/biophysics/talks/6Folta-Stogniew_tcm284-30259_tcm284-284-32.pdf)
[156] Peetermans,J.A. et al. (1987) : European Biophysics Journal 15:65-69.
[P001] Ito En Ltd. Bottled green tea drink and its manufacturing process. WO2012029131 A1 (2012.03,08)

Farmers’ Market at UNU in Tokyo

Highly-motivative farmers organize and hold farmers’ market every weekend in front of UNU (United Nation University).

In this market, Moriki farm will participate and sell their teas and related products.

Young tea farmer, Moriki Kazuya, has a great passion for tea cultivation, production, and making people enjoy teas.

We will enjoy shopping in his booth due to his funny personality and the flair of his products. The cute and elegant design of his products are exhibited in the webpage of Moriki farm.(Unfortunately described in Japanese only)

He and his father belong to the tea production cooperative of Yamaha-Hagima. Yamaha-Hagima tea production cooperative wined three awards in each competition of green tea in 2015, indicating highly sophisticated technique of tea cultivation and production

I hope you will enjoy their teas of fine quality, and communicating with Moriki-san also in the market.

 

–Details–
Date : 30th(sat) and 31th(sun) in Jan. (Days Moriki farm will join)
** This farmers’ market has a lot of participants from all Japan and is held in every weekend. Please check the participants and products in its official website.
Place : United Nations University in Shibuya-ku, Tokyo.
Access : The nearest station is Shibuya station.
As for how to make railway plan, please search using “JNTO Travel Planner”. (At the below part of this link page, we can look “-> JNTO Travel Planner”.)
** Please search “farmers market unu”.

 

Tea Notables Visited Makinohara

On 25th Jan, two notables writing various articles for teas visited and enjoyed Makinohara distinct.
Fortunately, I could have the pleasure of sharing some time to go to each place along with them.

In World Tea Museum “Ocha No Sato”, we saw a variety of items related to tea cultivation, production, processing, ceremony, culture etc.

01
Mr. Richardson explained about tea culture in Mongolia.
From the left side, Mr. Richardson, Sakano-san, Yamamoto-san, Steven, Ms. Hardie, respectively.
Mr. Richardson, “the tea maestro” as he say, is the owner of “Elmwood Inn Fine Teas”, writing a lot about teas worldwide. “Maestro” is derived from his former job, musician.
Ms. Hardie is one of the most prominent tea writers in Canada. We can read her posts in “The Daily Tea”.
Sakano-san is the CEO of “Soft-Lab”.
Yamamoto-san is the president of Katsumata Kaitaku Tea Production Cooperative.
Steven is a prefectural officer belonging to the division of multiculturalism.

02
Yamamoto-san explained about the miniature expressing tea plucking in the past time.

03
Yamamoto-san showed pamphlets illustrating “Ranji”, the special font of English described on the labels for the containers exported from Japan to foreign countries in the past time.
Beyond them, we can see the poster explaining about the traditional tea-grass integrated system so-called “Chagusaba Management”, which was designated as GIAHS (Globally Important Agricultural Heritage System) by FAO.

04
Various tea apparatus are exhibited.

05
Mr. Richardson told Ms. Hardie the mechanism of rolling machine so-called “Sojuki”, which is used for rolling and drying process to produce “Sencha”, steamed green tea.

06
07
We looked over the Japanese-style garden from the museum building. I felt “Wabi”-grace and “Sabi” elegance from the garden.
Beyond the garden, we saw a nice view of Ooi River and Mt. Fuji.
After visiting the museum, we looked tea plantation managed by Yamamoto-san.

08
Yamamoto-san told Ms. Hardie the status of tea plants in this season.

09
Fortunately, we could see the trimming by the machine, carried out by the colleague of Yamamoto-san.

Then, Yamamoto-san and his wife brewed his teas for us in his home.

10
Yamamoto-san brewed two types of tea, green tea and black tea.

11
The guests seemed to be satisfied with the teas by Yamamoto-san.
Mr. Richardson said that he could feel terroir.
I thought also and felt unique and original bouquet from each tea, as mentioned at the page of  “My Sweet Ambers“.

The last place we visited in that day was Shizuoka Prefectural Research Institute of Agriculture & Forestry Tea Research Center.
In this institute, we tasted the newest type of green tea resulted from the research project named as “the third generation Sencha”. In general, Sencha has lower aroma due to steaming in its production process, however, this new tea has a nice and more abundant aroma compared with general Sencha.

12

The director of the center brewed “the third generation Sencha”. The person with yellow cloth is a trainee from Sweden, Oscar Brekell.
Ms. Hardie gave a compliment the color of infusion is so nice. The color of infusion is clear as shown below.
14

And then, the director of Tea Research Center and Mr Oscar introduced the laboratory, which is open to tea farmers in order to develop their technique and create new products.

13
Mr. Oscar explained each machine in the lab.

The prominent guests seemed to be satisfied to the program to visit Makinohara. And hopefully, they will come to Makinohara area repeatedly.

It was a great pleasure for me to communicate and go along with them. Hopefully, I wish I will meet them again in Makinohara.
In the end, I’d like to say “Thank you so much for your visit! And, May Teas Fortune Be With You!”

 

Polyelectrolyte Complexes Affect Tea Taste and Mouthfeel? – Part 1

Tea has various polyelectrolyte, such as 4 types of catechins in green tea, pectins, polysaccharides, theaflavins and thearubigins in black tea, and so on.

We know these constituents determine tea taste.

In addition, complexes or aggregates of these polyelectrolyte could affect taste and mouthfeel of tea, in my personal opinion.

If laser light is applied to some solution which contain submicron size particles such as polyelectrolyte, the light scatters as depicted in some scientific blogs. We can see a red line of light scattering in the suspension. We obviously find the suspension turbid.

Tea infusion can also scatters laser light as follows, even though its color is clear as we can see through the wood grain of the table.

LightScatteringByTeaInfusion
This means tea infusion contains submicron-size particles, although this tea infusion doesn’t seem to be turbid.

What are these particles?
I guess these could be the complexes or aggregates of tea polyelectrolyte.

Polyelectrolyte can aggregate by some mineral ions such as calcium, ferric ion, etc. and bind such ions making complexes. I think lower infusion rate of tea polyelectrolyte under higher concentration of calcium ion, as clarified by Sipro et al.[140]

I’d like to continue to post such kind of personal speculation.

[140] Spiro M., Price W.E., Miller W.M., Arami M. (1987) :  Kinetics and equilibria of tea infusion: Part 8—the effects of salts and of pH on the rate of extraction of theaflavins from black tea leaf, Food Chemistry 25:117-126

Re-steeping could inspire expressive faces of green tea!

Green tea “Sencha” has a potential to be brewed more than three times.
In Japan, it is recommended to infuse green tea at low temperature at first infusion and then re-steep at higher temperature than the previous infusion. An example of water temperature to infuse deep-steamed green tea “fukamushi cha” is shown as follows.

Conditions-Table

In this condition, extraction behavior of each constituents determining tea taste is shown in the following picture, based on results measured by Sakamoto et al. [089].

InfusionRatio

The first infusion makes us enjoy umami due to amino acids and delicate taste with fresh aroma. In the case of higher grade one, these flavors keep longer and finish smoothly and more gracefully.
The second infusion has a nice balance of umami with bitterness and astringency. In the case of higher grade one, in some minutes after sipping it, aftertaste can keep longer and change to sweet gradually. In the supposition of the author, this grdual change in aftertaste to sweet would be caused by the conformation change of taste-determining polyelectrolyte such as catechins, tannin, saccharides and their complexes, due to the change in their surrounding chemical conditions such as electrochemical potential and oxidation-reduction potential.
The third infusion has more bitter and astringent taste derived from catechins.

In addition to these taste, we can enjoy the change in infusion color also, especially in case of deep-steamed green tea. Till the third infusion, its color is getting deeper green with the progress of re-steeping.

3infusions
As just described, we can find expressive faces of green tea by re-steeping.

Furthermore, we can arrange the flavor of green tea by adjusting water temperature and steeping time based on the extraction kinetics of each taste-determining constitution.

In my personal opinion, I prefer longer infusion time at 1st infusion, resulting in more umami and fine aftertaste for me.

Please try various arrangement of infusion conditions as you like!

 

<Reference>
[089] Sakamoto A., Nakagawa M., Sugiyama H., Horie H. (2002) The compositions of the respective infusions of Sencha brewed three times, Tea Research Journal94:45-55 (in Japanese)

How to enjoy hot teas! – An unique brewing technique

Based on the Tea Council of the USA, January 12th is recognized as “National Hot Tea Day” in USA., suggesting that the coldest month makes us to be eager to drink hot tea.

Hot teas provide us warmness, soothing sense of relief, power to live, comfortable time with family and loved one, especially in cold days. In the bedtime scene, a nightcap tea invites us smoothly to a comfortable dream.

In general, it is recommended to brew Japanese green tea at lower temperature, resulting in better taste due to the difference in infusion rate of each constituent determining taste.
At lower temperature, amino acids responsible to umami and delicate taste diffuse faster(*1) than caffeine or catechins, responsible to bitter or astringent taste. This tendency was clarified in the reference[091] described at the end of this post and depicted as follows.

InfusionKinetics

If we brew Japanese green tea at high temperature around 100 degree Celsius, constituents of bitter and astringent taste will be infused more. While we know such fact, nevertheless we would like to enjoy hot green tea of better taste as soon as possible.

Yutaka Koizumi, a past president of the Prefectural Research Center of Tea Industry in Shizuoka, told a nice idea to enjoy umami-rich green tea at higher temperature very easily as shown below.

1) Soaking tea leaves in water for minutes(*2).
Loose leaf tea is soaked in a little amount of water for some minutes.
In this process, amino acids are infused.

InfusionProcess01
2) Adding hot water
Pour hot water to the tea pot, and then brew tea into tea cups.

InfusionProcess02
Only two processes will provide better taste tea at warm temperature.

In my personal opinion, this method can be apply to Japanese black tea also.

I hope you will find this method very helpful.

 

< Note >
(*1)  Based on the Fick’s first law and Stokes-Einstein equation, diffusion flux of each constituent increases as molecular size increases.

DiffusionKinetics

(*2)Soaking time can be extended. I often soak before going to work and pour hot water after coming home. More than 10 hours soak does not result in bitterness and astringency so much. I feel a little bit bitterer and more astringent.

 

<References>

[091] Ikeda S., Nakagawa M., Iwasa K. (1972) : Relation between Infusing Condition of Green Tea and Soluble Component, Tea Research Journal 37:69-78 (in Japanese).

 

World O-Cha Festival in 2016

World O-Cha Festival will be held in Shizuoka prefecture in spring and autumn 2016.

The spring festival will be held between 5/13 and 5/15, and the autumn festival will be held between 10/27 and 10/30. The details are described in the official website.

The overview of its program is almost prepared and the details will be arranged till the festival.

The festival has various programs such as the collaboration with music, garden making, flower, pottery making etc., tea tourism, exhibition of teas and the related products, tea ceremonies, seminars and so on.

It is not necessary to apply. Please enjoy freely.
Additional information will be posted in “Event” and “Guide for trips” pages.
And if you need more additional information, please contact the organizer by e-mail, whose address is described at the bottom of its official website.
(It is also possible to contact through this blog comment, I cannot guarantee to reply all comments)

Shitoro-Yaki, one of the best Japanese potteries for tea

In the spring of 2016, Japanese tea cafe will open in USA supported by Cool Japan Fund (source:worldteanews.com). In this cafe, we can enjoy not only tea, we can enjoy Japanese pottery also! The pottery shown or provided in the café is “Hasami-yaki” from Nagasaki prefecture, located in southwest of Fukuoka.
Unfortunately, the sophisticated Japanese pottery in Shizuoka will not be exhibited or sold there.

So “Shitoro-Yaki” is introduced in this post, it is one of the best Japanese potteries for tea or tea ceremony.

Shitoro-Yaki is made in Kanaya area located north part of Makinohara plateau. This area has abundant clay minerals of fine quality, perfect for Japanese pottery.

Features of “Shitoro-Yaki”
1. Resistance to humidity
– In the process of Shitoro-Yaki production, the vitrification is carried out at higher temperature to tighten the body of pottery, resulting its resistance to humidity. Perhaps, this would be because of higher content of clay mineral in its raw material. This feature is suitable to store loose leaf tea for long time.

2. Specific color – dark or subdued color
– Shitoro-Yaki has slightly yellow or red color with subdued atmosphere. Its raw material contains somehow higher content of ferric oxide comparatively. This would be the reason of its yellow or red color.

Kobori Enshu, one of the most famous tea masters in Edo era like Senno-Rikyu, loved these features. In the result, Shitoro-Yaki is certificated as one of the “Enshu Nana Kama” – 7 pottery loved by Enshu.

The author of this blog has joined a experience program of Shitoro-Yaki crafting. In this program, the craftworker gave participants some unique tea pots as presents shown below.

Shitoro-Yaki01

We can infuse tea by using this pot as follows.

Shitoro-Yaki02
There are some crafts that provide such kind of experience program. For getting the details, we should contact with the Shimada city Tourist Association*.

*The webpage of the Shimada city Tourist Association describes articles in Japanese only. If you need, you can see the webpage of Shimada city. By clicking “Foreign Language” button, you can read explanations in English, Chinese, Korean, and Portuguese. Unfortunately there are no descriptions for the experience program of Shitoro-Yaki crafting in the page of Shimada city. If you contact with Shimada city, you may get some information in English.

 

May Teas & Fortunes Be With You!

Wishing you a happy and joyful life in 2016! And hopefully with tea!!
I hope tea and tea products would provide you many fortunes.

In Japan, the first sunshine so-called “Goraikou” has a special power to make us happy. Hopefully, I wish the sunshine through tea garden will bring you happiness.

01 SunshineThroughTeaPlants01

02 SunshineThroughTeaPlants02

 

In this day, the sky was so clear, resulting in so nice view of Mt. Fuji beyond tea gardens. It seems that the scared mountain Fuji empowers tea gardens!

03 MtFujiBeyondTeaGardens

 

Scenes of the dawn in the mountain recalled me a phrase in “The Pillow Book” by Sei Shounagon, an ancient poet in Japan as follows.

04 SpringDawn

Such scene came into my view like below.

05 SunshineCreepingMakesMountainFaintRed

On the tea garden located the edge of mountain, I could watch that the color of tea plants surface changed from slightly dark to faint red.

05 SunshineCreepingMakesFaintRedInTeaGardes

The sky in this day was too clear for me to find purplish cloud tail over them.

The first day of 2016 provided so wonderful scenes!!
*As for the title, MTFBWY means not only “May The Force Be With You”, it does mean “May Teas & Fortunes Be With You” also, just in my personal opinion 🙂

I hope Shizuoka teas bring you a prosperity!